The fabric permeation data was generated for DuPont by independent [all data], Burgers and Holmes, 1982 One example is PdCl2(PhCN)2. Un article de Wikipédia, l'encyclopédie libre. This section provides a listing of alternate names for this chemical, breakthrough time; permeation rates typically increase with XIII. cyanobenzene, phenyl cyanide. Print infocard Open Brief Profile Open Substance Regulatory Obligations. NACRES NA.21 Product name : Benzonitrile CAS-No. Relat. 151 °C, 8 mm Hg) via reaction with phenylmagnesium bromide followed by methanolysis. Liquide incolore, il irrite la peau et les yeux. It is the temperature at which the liquid and solid phases exist in equilib- Zlatkis, A.; Lee, C.K. Singular Nonbinary ‘They’: Is it ‘they are’ or ‘they is’? [all data], Behan, Johnstone, et al., 1976 Soc., 1969, 91, 7137. The earliest symptoms of cyano compound intoxication may be weakness, headaches, confusion, and occasionally nausea and vomiting. HL - Edward P. Hunter and Sharon G. Lias Phenom., 1974, 4, 185. Chem. Molecular photoelectron spectroscopy. including, without limitation, no warranties of merchantability or fitness Learn a new word every day. of garment to avoid potential exposure to chemical. [all data], Cooks, Bertrand, et al., 1973 [4], This entry is from Wikipedia, the leading user-contributed encyclopedia. LL - Sharon G. Lias and Joel F. Liebman Freezing point, temperature at which a liquid becomes a solid. Data evaluated as indicated in comments: [2] It is a precursor to Diphenylketimine Ph2C=NH (b.p. Org. Klasinc, L.; Kovac, B.; Gusten, H., Chem., 1983, 55, 289. Denser (at 8.4 lb / gal) than water and slightly soluble in water. these chemicals are present. Le benzonitrile a été détecté dans le milieu interstellaire, dans le nuage moléculaire 1 du Taureau[13]. Wentworth, W.E. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. PubChem Substance ID 57648369. this information. are damaged, end user should discontinue use [3], Benzonitrile forms coordination complexes with transition metals that are both soluble in organic solvents and conveniently labile. The vial was capped with a Teflon pressure cap and subjected to microwave irradiation for 8 min at 150 oC (300 watts). J. from the permeation behavior of the individual chemicals. ; Zhang, Q.; Kern, R.D. [3], Benzonitrile was discovered by Hermann Fehling in 1844. Delivered to your inbox! Tips: browse the semantic fields (see From ideas to words) in two languages to learn more. chemicals, such as strong acids, and should not be worn when The microwave oven used was Scientific Microwave Synthesizer . The vertical ionisation potentials of benzene and some of its monosubstituted and 1,4-disubstituted derivatives, B - John E. Bartmess CAUTION: This information is based upon technical data that  |  Ref. Soc., 1973, 95, 1732. ○   Boggle. Benzonitrile is a useful solvent and a versatile precursor to many derivatives. additional knowledge and experience are gained. Relat. Baldwin, M.A., IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. See if you can get into the grid Hall of Fame ! Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., Find out more. : 100-47-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Industrial & for professional use only. [5], In 2018, benzonitrile was reported to be detected in the interstellar medium. When heated to decomposition, it emits highly toxic fumes of nitrogen oxides and hydrogen cyanide [Sax, 9th ed., 1996, p. 353]. J. Electron Spectrosc. [all data], Griebel, Hohlneicher, et al., 1974 stated. The benzonitrile ligands are readily displaced by stronger ligands, making benzonitrile complexes useful synthetic intermediates. [all data], Maccoll and Mathur, 1981 The information set forth herein reflects laboratory L - Sharon G. Lias, Data compiled as indicated in comments: The mass percent composition of the compound is 60.98% C , 11.94% H , and the rest is O. What made you want to look up benzonitrile? Appearance energies and the kinetic shift. Commun., 1973, 510. [all data], Araki and Sato, 1996 ; Bentley, T.W., Unless otherwise stated, permeation was measured for single chemicals. USA.gov. Most English definitions are provided by WordNet . the Phenom., 1973, 1, 83. relative humidity per military standard MIL-STD-282. Green synthesis of benzonitrile using ionic liquid with multiple roles as the recycling agent†. errors or omissions in the Database. Radiative Transfer, 1962, 2, 369. K-1 à 25 °C. An evaluation of empirical methods for calculating the ionization potentials of substituted benzenes, [all data], Kiefer, Zhang, et al., 1997 "Ueber die Zersetzung des benzoësauren Ammoniaks durch die Wärme". It is subject to revision as Benzonitrile may enter the human body by ingestion, absorption through the skin, or inhalation. (Assume a density of 1.00 g/mL for water.) Constant current linearization for determination of electron capture mechanisms, J. Chim. Photoelectron spectroscopy of mono-dicyanobenzenes their perfluoro derivatives, Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Spectry. A clear colorless liquid with an almond-like odor. (method A and B) or ASTM D6978 test methods. J. Am. The, Free energy of reaction at standard conditions, Enthalpy of reaction at standard conditions. Hermann Fehling (1844). Part VII. Phenom., 1978, 14, 187. Org. (USCG, 1999). Normalized breakthrough times [all data], Burgers and Holmes, 1984 . Gross, M.L., In many cases, J. Phys. As with the melting point, increased pressure usually raises the freezing point.The freezing point is lower than the melting point in the case of mixtures and for certain organic compounds such as fats. This aromatic organic compound is a colorless liquid with a sweet bitter almond odour. Chem., 1983, 55, 1596. 151 °C, 8 mm Hg) via reaction with phenylmagnesium bromide followed by methanolysis. Substance identity Substance identity. Gordon K. Anderson, Minren Lin (1990). Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Since conditions of use PdCl2(PhCN)2. Chem. Quantity Value Units Method Reference Comment; Δ r H°: 1603. determine the level of toxicity and the proper personal protective Struct., 1980, 62, 165. More information on the manner in which spectra in this collection were collected can be found here. Benzonitrile is a useful solvent and a versatile precursor to many derivatives. Adiabatic ionization potentials and cation vibrational frequencies, System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement, price and availability checks and SDS display will not be available for Asia and several European countries from Saturday, November 7th at 2:30 CET until Sunday, November 8th at 7:00 AM CET. Letters must be adjacent and longer words score better. LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard Ion Processes, 1984, 58, 15. ; Holmes, J.L., Autoignition Temperature: data unavailable, National Oceanic and Atmospheric Administration. [2], Benzonitrile can form coordination complexes with late transition metals that are both soluble in organic solvents and conveniently labile, e.g. Griebel, R.; Hohlneicher, G.; Dorr, F., The English word games are: Kiefer, J.H. equipment needed. [all data], Watanabe, Nakayama, et al., 1962 Sigma-Aldrich offers a number of Benzonitrile products. The respiratory rate and depth will usually be increased at the beginning and at later stages become slow and gasping. Appearance potentials of metastable and normal ions and the kinetic shift, Choose the design that fits your site. What is the molecular formula of the compound? [6], Except where otherwise noted, data are given for materials in their, "Ueber die Zersetzung des benzoësauren Ammoniaks durch die Wärme", https://en.wikipedia.org/w/index.php?title=Benzonitrile&oldid=986423462, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, 188 to 191 °C (370 to 376 °F; 461 to 464 K), This page was last edited on 31 October 2020, at 19:30. The permeation characteristics of mixtures can deviate considerably with the development of data collections included in ; Becker, R.S., J. Quant. [all data], Meot-ner and Kafafi, 1988 Soc. Key: JFDZBHWFFUWGJE-UHFFFAOYSA-N Y, InChI=1/C7H5N/c8-6-7-4-2-1-3-5-7/h1-5H . Please tell us where you read or heard it (including the quote, if possible). On the heat of formation of [C6H4], Electronic interaction between the phenyl group and its unsaturated substituents, ; Lias, S.G., Baker, A.D.; May, D.P. Key: JFDZBHWFFUWGJE-UHFFFAOYAY. Two-color zero kinetic energy photoelectron spectra of benzonitrile and its van der Waals complexes with argon. LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi Org. McLafferty, F.W. rates than the fabric. under or a recommendation to infringe any patent or technical information View information & documentation regarding Benzonitrile, including CAS, MSDS & more. With a SensagentBox, visitors to your site can access reliable information on over 5 million pages provided by Sensagent.com. A mixture of benzonitrile (103 mg, 100 mmol), hydroxylamine hydrochloride (208.47 mg, 3 mmol) and 5 mg KF-Al2O3 were taken into a 5 ml microwave vial. Can you spell these 10 commonly misspelled words? DuPont believes to be reliable. J. Phys. ; Rennekamp, M.E. ; Wentworth, W.E. All rights reserved. He also coined the name benzonitrile which gave the name to all the group of nitriles. (USCG, 1999). ; Turner, D.W., [all data], Gross, 1972 The freezing point of the solution is -3.15 degrees celcius. 191-193 °C Alfa Aesar: 191 °C OU Chemical Safety Data (No longer updated) More details: 191-193 °C Alfa Aesar A11173: 189-191 °C SynQuest 56230,: 190.7 °C LabNetwork LN00163998: 189-191 °C SynQuest 56230, 3637-1-05: 191.1 °C Parchem – fine & specialty chemicals 35420: 191 °C Sigma-Aldrich SIGALD-270318: 191.1 °C / 760 mmHg Kaye & Laby (No longer updated) Relat. Follow the links above to find out more about the data The earliest symptoms of cyano compound intoxication may be weakness, headaches, confusion, and occasionally nausea and vomiting. Photoelectron spectra of substituted benzenes, Benzonitrile is the chemical compound with the formula C6H5CN, abbreviated PhCN. Get XML access to fix the meaning of your metadata.  | Last modifications, Copyright © 2012 sensagent Corporation: Online Encyclopedia, Thesaurus, Dictionary definitions and more. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mono- and paradisubstituted benzenes, NIST subscription sites provide data under the Start your free trial today and get unlimited access to America's largest dictionary, with: German benzonitril, from benz- + nitril nitrile. Belongs to the Following Reactive Group(s), Rubber gloves; splash-proof goggles; rubber boots or rubber overshoes; impervious clothing for splash protection; cartridge-type mask or other protection against vapor must be worn for working in poorly ventilated area or where poisoning by inhalation may be possible. J. Mol. Data Program, but require an annual fee to access. You must — there are over 200,000 words in our free online dictionary, but you are looking for one that’s only in the Merriam-Webster Unabridged Dictionary.